Good answer can be found here, taken from a physical standpoint.
The terms n- and p-type doped do only refer to the majority charge carriers. Each positive or negative charge carrier belongs to a fixed negative or positive charged dopant.
p and n type materials are NOT positively and negatively charged.
An n-type material by itself has mainly negative charge carriers (electrons) which are able to move freely, but it is still neutral because the fixed donor atoms, having donated electrons, are positive.
Similarly p-type material by itself has mainly positive charge carrier (holes) which are able to move relatively freely, but it is still neutral because the fixed acceptor atoms, having accepted electrons, are negative.
http://physics.stackexchange.com/questions/81488/how-can-doped-semiconductor-be-neutralhttps://physics.stackexchange.com/questions/81488/how-can-doped-semiconductor-be-neutral