Well, the other people who answered your question have shown why it is the case. Now use the math so show what the equations tell us. We have the following circuit:
simulate this circuit – Schematic created using CircuitLab
Using KCL, we can write:
$$\text{I}_\text{i}=\text{I}_1+\text{I}_2\tag1$$
Using KVL, we can write:
$$
\begin{cases}
\text{I}_\text{i}=\frac{\text{V}_1-\text{V}_2}{\text{R}_1}\\
\\
\text{I}_2=\frac{\text{V}_2-\text{V}_3}{\text{R}_2}\\
\\
\text{I}_\text{i}=\frac{\text{V}_5}{\text{R}_3}\\
\\
\text{I}_2=\frac{\text{V}_4-\text{V}_5}{\text{R}_4}\\
\\
\text{I}_2=\frac{\text{V}_3-\text{V}_4}{\text{R}_5}\\
\\
\text{I}_1=\frac{\text{V}_2-\text{V}_5}{\text{R}_6}
\end{cases}\tag2
$$
I used Mathematica to solve this system of equations, and it gave me:
In[1]:= FullSimplify[
Solve[{Ii == I1 + I2, Ii == (V1 - V2)/R1, I2 == (V2 - V3)/R2,
Ii == V5/R3, I2 == (V4 - V5)/R4, I2 == (V3 - V4)/R5,
I1 == (V2 - V5)/R6}, {I1, I2, V1, V2, V3, V4, V5}]]
Out[1]= {{I1 -> (Ii (R2 + R4 + R5))/(R2 + R4 + R5 + R6),
I2 -> (Ii R6)/(R2 + R4 + R5 + R6),
V1 -> (Ii (R1 + R3) (R2 + R4 + R5) +
Ii (R1 + R2 + R3 + R4 + R5) R6)/(R2 + R4 + R5 + R6),
V2 -> (Ii R3 (R2 + R4 + R5) + Ii (R2 + R3 + R4 + R5) R6)/(
R2 + R4 + R5 + R6),
V3 -> (Ii R3 (R2 + R4 + R5) + Ii (R3 + R4 + R5) R6)/(
R2 + R4 + R5 + R6),
V4 -> (Ii (R3 (R2 + R4 + R5) + (R3 + R4) R6))/(R2 + R4 + R5 + R6),
V5 -> Ii R3}}
The power in resistor \$\text{R}_6\$, gives:
$$\text{P}_{\text{R}_6}=\left(\frac{\text{I}_\text{i}\left(\text{R}_2+\text{R}_4+\text{R}_5\right)}{\text{R}_2+\text{R}_4+\text{R}_5+\text{R}_6}\right)^2\text{R}_6\tag3$$
The maximum occurs when:
$$\frac{\partial\text{P}_{\text{R}_6}}{\partial\text{R}_6}=0\space\Longleftrightarrow\space\text{R}_6=\dots\tag4$$
Using Mathematica, gives:
In[2]:= FullSimplify[
Solve[{D[((Ii (R2 + R4 + R5))/(R2 + R4 + R5 + R6))^2*R6, R6] == 0,
R6 > 0 && Ii > 0 && R2 > 0 && R4 > 0 && R5 > 0}, R6]]
Out[2]= {{R6 -> ConditionalExpression[R2 + R4 + R5,
R5 > 0 && R4 > 0 && R2 > 0 && Ii > 0]}}
So, the maximum occurs when:
$$\text{R}_6=\text{R}_2+\text{R}_4+\text{R}_5\tag5$$
And the maximum is then:
$$\hat{\text{P}}_{\text{R}_6}=\frac{\text{I}_\text{i}^2\left(\text{R}_2+\text{R}_4+\text{R}_5\right)}{4}\tag6$$