You can't really script the IDE. It's not designed for that. You can of course run the compiler, assembler, librarian, and linker directly without using the IDE. In fact, this is how I build all my PIC projects. I use the IDE only for debugging. The reason I do this is to allow for automatic builds of PIC firmware as part of a larger process, and to apply some of my own tools in the chain from source code to HEX file. For example, I run all my ASM30 and MPASM source code thru my preprocessor.
For how to run the various tools directly, read the manual, which in this case is MPLAB ASSEMBLER, LINKER AND UTILITIES for PIC24 MCUs and dsPIC DSCs User's Guide, DS51317.
However, rebuilding the firmware each time sounds more complicated than necessary. If you are only changing some data at a known location in program memory, then you can do this with a simple HEX file editing program. I do this sort of thing occasionally, often to create a HEX file with a unique serial number from a master HEX file. I make a program that reads in a HEX file into arrays in memory, usually one for executable program memory, config bits, EEPROM initial data, and user ID locations. The program then modifies the data as necessary, and writes the result out to a new HEX file.
It's usually a good idea to put firmware info at a known fixed address when doing this. I usually put the firmware type ID, version number, and sequence number in the three bytes of the program memory word at 800h. That is far enough into executable code so that the section between start and 800h is large enough to utilize efficiently, but not so far as to be past the end of program memory for any reasonable PIC. You make this a fixed code section and let the linker place relocatable sections around it. Here is a example from a recent project:
;*******************************************************************************
;
; Constants in program memory so that HEX file editing tools know the version
; of this firmware.
;
.section .fwinfo, code, address(0x800)
.pword fwtype | (fwver << 8) | (fwseq << 16)
This allows the HEX file tool to veryify that it is working on the right type of HEX file, and to display this information at run time.