Since resistance is defined as:
$$ R= \frac{E}{I}$$
In the case you've mentioned, by citing a particular forward voltage (Vf) dropped across an LED with a particular forward current (If) through it, we have
$$ R= \frac{Vf}{If} = \frac{2V}{0.0075A} =267 \text{ ohms}$$
However, since an LED's Vf will stay fairly constant while its If varies since the LED isn't ohmic, its resistance won't remain constant, and its calculated resistance will only be valid at the particular Vf and If cited.
For example, if the LED you you were referring to developed a Vf of 2.1 volts with an If of 15 mA through it, then its resistance under those conditions would be:
$$ R= \frac{Vf}{If} = \frac{2.1V}{0.015A} = 140 \text{ ohms,}$$
which, as you can see, is quite different from the first case.
Following is an interesting plot of forward voltage and resistance as a function of forward current for a randomly picked (junkbox) 20 mA red LED.
The current through, and voltage dropped across the LED were measured, and the resistance was calculated as discussed earlier.
Enjoy! :)