simulate this circuit – Schematic created using CircuitLab
Figure 1. Circuit redrawn with positive rail on top and negative rail on bottom.
Voltage is a measure of the "electrical potential difference" between two points. This is analogous to height difference between two points: you place the end of the tape measure at one point (your reference) and measure the distance to the other. Common practice is to use a standard reference such as the ground or sea-level.
The standard schematic layout convention makes this a little easier to understand. We draw the circuits with the highest potential (voltage) at the top and lowest at the bottom. It is also common practice to add a ground point on the circuit whether or not it is connected to real earth. All voltages can then be referenced to this point. Using the reference we can now say that "C is at 6 V with respect to ground".
It should now be clear that if A is 4.5 V above ground and C is 6 V above ground then C is 1.5 V higher than B.
Can anyone tell me what is going on? Where is the electricity traveling to and from in question 3?
Since your multimeter has a very high input resistance there is almost no current flowing from B to C - we are only measuring the difference in voltage. If current were to flow then we would upset the circuit we are trying to measure and the readings would be in error. (In this example with 100 Ω resistors a 1 MΩ multimeter would make hardly any difference.)
Does the voltmeter create a new path for the electricity?
Yes but usually it's negligible. We only have to worry about it if the resistance values are high and the multimeter could affect the circuit under test.
Is there any other way to derive the 1.5V?
The method you have used is the simplest. Figure out the voltage at each point and subtract to get the relative voltages.
So the voltmeter doesn't really affect the circuit at all, it just takes a peek at the voltage at the two points and tells you the difference?
Figure 1. The ICE Supertester 680R analogue multimeter showing the DC and AC loading. The author had one of these for many years.
You've got it. An ideal voltmeter would have infinite resistance and wouldn't load the circuit it's measuring at all and to do this it would need infinite input resistance. The old analog multimeters were typically 20 kΩ/V and the user had to take this into account when making a reading. For example, when on the 10 V DC range the load on the circuit would be 20k * 10 = 200 kΩ and this could load a high impedance circuit significantly. Modern digital meters are usually > 10 MΩ input impedance so this is less of a problem.
Also for future use, is there a standard place to put the ground point in a circuit?
On a circuit with a single supply the normal convention is that battery negative is the ground reference. Almost all digital logic is designed for a common negative so it makes sense to use this. There are circuits that require a negative supply and circuits that require dual or multiple supplies. so the ground reference can be placed wherever makes sense for that application.
Further reading: my answer to Few questions about basic concepts in electronics may give another slant on the ground question which you may find helpful.