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I am using a switching voltage regulator to go from 5V to 3.3V, 1A of output current. The datasheet specifies 22uF ceramic capacitors for the input and output. Can I use 2 10uF capacitors instead of one 22uF capacitor?
Besides the difference in frequency response (10uF has a higher resonant frequency), is there a reason why one 22uF would be better than using two 10uF?
Two is usually better than one for ceramic.
In a non-electrolytic capacitor and electrolytic capacitors with solid electrolyte the metallic resistance of the leads and electrodes and losses in the dielectric cause the ESR. Typically quoted values of ESR for ceramic capacitors are between 0.01 and 0.1 ohms. ESR of non-electrolytic capacitors tends to be fairly stable over time; for most purposes real non-electrolytic capacitors can be treated as ideal components. (Wikipedia on ESR)
The ESR for the capacitors are limited by the manufacturing process and related more to physical size than value. Depending on the type of capacitor being used, the ESR of two in parallel will be less than a single capacitor of twice the value.
If you look at this Murata catalog you will see that the ESR is defined for a range of physical sizes rather than per capacitance value.
Two 10uF would probably be better, due to them likely having lower ESR or equivalent series resistance. If it calls for ceramic, stick to ceramic. Don't change type of capacitor, as the different types can have drastically different ESR. The only reason one 22uF would be better is because there is one less component to place on the PCB and might cost slightly less.
