From my high-voltage class I remember that the maximum field strength is about 30 kV per centimeter. And this is for a homogenous electrical field, e.g. between large spherical conductors, where the conductor diameter is large compared to the gap distance.
Hence, for 800 kV you need an air gap of at least 25 cm, between spherical conductors with a radius of, say, over 1 meter. Just google at "high voltage lab" and you will see such spheres. The Vandergraaf Generator, sketched in another answer, has such a sphere, and its diameter and distance to Earth limits its top voltage.
Looking at your picture with thin wires expecting to carry 800 kV, I do not see a homogeneous field, and the distance between the conductors is in the range of millimeters. If you charge up those wires, you will get sparking long before you reach 30 kV. Not only sparking at the end of the conductors, through air, but also through the plastic insulation.
For illustrations about the difference between conductor shapes, search for Rogowski Profile or Electrode, e.g. here
So the question is not how to transform a low voltage to a high voltage, but how to prevent sparking.