Your pic16f1825 does not have any general purpose outputs so you're using a pca9554 which has 8 General Purpose IOs switched via I2C. The relay needs to be connected to one of the pca9554 IOs (labeled with a P in the datasheet).
The pca9554 can output 5v at 20ma. If your relay will switch with that current and voltage then great. If not you'll need the pca9554 to switch something that can, a transistor switch would be a normal choice. You then need to connect the pic to the pca9554 and use the datasheet to set the appropriate registers for output (by default they're configured as inputs) and then send the command to set the pin high.
A schematic of your circuit would be useful as I've made some assumptions here.