I'm getting a little confused with the convention of saying that "holes in a semiconductor will move from p-side to n-side and electrons will move the opposite way". I have no trouble with the concept itself, it just seems to me that an electron moving from one side to the other would mean it left a hole behind where it used to be?

Am I understanding it correct that we just think of electrons leaving behind holes as "holes moving" or do I actually misinterperet the way this works?

• think of a row of seats at a theatre .... one empty seat in the middle ... one empty seat at one end ... two people arrive and ask everyone to move one seat over ... if the people move one at a time, then that empty seat in the middle of of the row can be thought of as travelling to the end of the row – jsotola Aug 31 '19 at 20:49
• ...and sometimes there is an extra person (donor atom) standing in a row. When that person moves they don't leave a hole behind. A hole is not simply the result of an electron moving, it is an electron leaving a covalent bond in the silicon lattice. – Elliot Alderson Aug 31 '19 at 21:08
• @jsotola I understand this concept, but I still think it would be silly to describe something that is literally the abscence of something as "moving". Isn't this just more confusing or is it actually useful to think this way? – C. K. Aug 31 '19 at 21:28
• @ElliotAlderson But for a hole to "move", an electron always have to leave, right? – C. K. Aug 31 '19 at 21:29
• @MariusGulbrandsen A lot of people like the "a hole is just the absence of an electron" model, but I find it to be confusing, and therefore a bad model, for the reasons you have stated. It also isn't an accurate description of what is happening. – Matt Aug 31 '19 at 21:34

From your quote it sounds like you are learning about charge carrier diffusion in a P-N junction. When those electrons and holes diffuse they don't leave behind a mobile charge carrier of the opposite type. They do however leave behind an ionized dopant atom, which is a fixed charge of the opposite type.

When dealing with semiconductors we two different mobile charge carriers: electrons and holes, as well as two energy bands where they can exist: valence and conduction. When talking about electrons and holes in a semiconductor, we mean electrons in the conduction band, and holes in the valence band. When these carriers are in the other band, they don't contribute to conduction, so we ignore them.

Many people like to think of a hole as a missing electron, but I think that is a bad description of the system for a few reasons. First, it is important to treat electrons and holes separately as their own individual particles. You can't rewrite all of semiconductor physics to work with just one carrier type (you probably can, but it would be much more complicated) Second, as previously mentioned, electrons and holes contribute to current when they are in different energy bands. So, a hole in the valence band moving is very much not the same thing as an electron in the conduction band moving in the opposite direction. In fact, the Hall effect relies on this to be the case.

Am I understanding it correct that we just think of electrons leaving behind holes as "holes moving" or do I actually misinterperet the way this works?

You can generate an electron-hole pair by moving an electron from the valence band to the conduction band, which results in +1 electron in the conduction band, and also +1 hole in the valence band. But from your quote it sounds like you are talking about carrier diffusion. In which case, no, electrons and holes moving around within a single band do not leave behind a carrier of the other type. They might, however, leave behind an ionized dopant atom, which is a fixed charge.

You are going to have a much easier time with semiconductor physics if you think of holes as just another type of particle, similar to electrons but with a positive charge (and a different mass).

To address some concerns from the comments I have included here some quotes from Solid State Physics by Ashcroft and Mermin page 227-228. This discussion relates to where holes come. Once you determine your material's electronic band structure you may do the following:

It therefore suffices to examine how electrons respond to applied fields to learn how holes do. The motion of an electron is determined by the semiclassical equation:

$$\\hbar \mathbf{\dot k}=(-e)\left(\mathbf E+\frac{1}{c}\mathbf{v}\times\mathbf H\right)\$$ (12.22)

Whether or not the orbit of the electron resembles that of a free particle of negative charge depends on whether the acceleration , $$\d\mathbf v/dt\$$, is or is not parallel to $$\\mathbf{\dot k}\$$. Should the acceleration be opposite to $$\\mathbf{\dot k}\$$, then the electron would respond more like a positively charged free particle. As it happens, it is often the case that $$\d\mathbf{v}/dt\$$ is indeed directed opposite to $$\\mathbf{\dot k}\$$ when $$\\mathbf{k}\$$ is the wave vector of an unoccupied level

It goes on to explain why this happens which is outside the scope of this question, and ends with:

we find that as long as an electron's orbit is confined to levels close enough to the band maximum for the expansion (12.23) to be accurate, the (negatively charged) electron responds to driving fields as if it had a negative mass $$\-m^*\$$. By simply changing the sign of both sides, we can equally well (and far more intuitively) regard Eq (12.22) as describing the motion of a positively charged particle with a positive mass $$\m^*\$$.

So yes, the electron/hole model allows for you to look at the system as two different particles of the same charge, but one has a negative mass, or you can model the system as two particles with the same sign mass, but opposite sign charges.

The takeaway is still that electrons and holes are two different things and the "holes are just missing electrons" model is inaccurate and does not work (again, see the Hall effect).

• Whats the numeric value of charge of hole? If it's a different particle, then I believe it should have some charge and positive charge of course. I once had the same confusion. The teacher just told me that hole is a positive charge but I found it to be a vacant space. I can see your good explanation why this concept is misleading but what if I want to measure the charge of hole? – Giga-Byte Sep 1 '19 at 1:46
• @JuneStar The charge of a hole is the same as the charge of an electron, but positive: 1.602e-19 C. Holes are more real than a lot of people give them credit for. They show up at the quantum level in a semiconductor and are just as real as the free electrons in the semiconductor. (Another valid interpretation of the results of the quantum model is a particle with a negative charge and a negative mass. But we decided that positive charges make more sense than negative masses.) Im not sure about measuring their charge. I could divise some tests but they all make some assumptions. – Matt Sep 1 '19 at 2:02
• Can holes exist when there is no any movement of electrons? – Giga-Byte Sep 1 '19 at 2:09
• @JuneStar We cant really have "no movement of electrons" at any temperature above 0 K. An electric field that would cause holes to move will also cause electrons to move. Concentration gradients cant exist in only one carrier type either. But its not the electron movement thats enabling hole movement. You can shrink the electron concentration to be many orders of magnitude below the hole concentration. Then you will effectively have (net) hole movement without electron (net) movement, verified by Hall measurements. – Matt Sep 1 '19 at 2:15
• @elliot : Intuitive models of quantum phenomena are often misleading. – hotpaw2 Sep 1 '19 at 3:28

Both 'hole' and 'electron' are models for what actually happens. It turns out that they can both be modelled as a quantum mechanical 'particle'. These are the best / easiest models to to use to understand semiconductor operation.

However, 'electron' is rather closer to our limited classical touchy-feely idea of reality than 'hole' is, which is why more of us grok electrons than holes.

Am I understanding it correct that we just think of electrons leaving behind holes as "holes moving" or do I actually misinterperet the way this works?

I think the biggest problem with your question there is the word 'just'. No, it's not 'just' this, it's much more complicated.