The water pump is likely specified to run off 5 V supply, and consumes up to 150 mA depending on load conditions and/or motor manufacturing tolerances. A pump consumes more current (and thus more power) if it's working against more back pressure.
We can imagine that the equivalent circuit of the pump connected to a 5 V supply looks something like this:

simulate this circuit – Schematic created using CircuitLab
This is extremely simplified, but essentially, the pump looks like a winding resistance in series with a voltage source that represents the back EMF (electromotive force) from the pump motor. We'll ignore winding inductance since this is pretty much a steady-state problem.
The back EMF is inversely proportional to the load on the pump. It will be zero volts when the pump is working hardest and trying to generate the most torque (ie: the rotor is blocked, or the pump is dead-headed). It will be almost at the supply voltage of 5 V when the pump is very lightly loaded, such as pumping against almost no backpressure. For certain types of pumps, it can be greater than the supply voltage if water is being pushed through the pump by an external pressure, in which case the pump is actually acting as a hydro generator.
Now, when you try inserting your 33 ohm resistor, the following happens:

simulate this circuit
Short answer to your question: the motor in the pump is starved for current by the addition of the series resistor, so it cannot get enough current to generate enough torque to start rotating. Since it's not rotating, it never develops a back EMF, and all the voltage applied to the motor is dropped across its winding resistance.
We can actually compute the winding resistance, since you've essentially inadvertently created a blocked rotor test. Your supply voltage sagged to 4.6 V, and the voltage at the pump terminal is 2.5 V. We can state that the current through the circuit is thus:
$$I = \frac{4.6V-2.5V}{33\Omega} = 64 mA$$
Since the back EMF is zero, and the voltage at the motor terminal is 2.5V, we can state:
$$ R_{winding} = \frac{V_{motor}}{I_{motor}} = \frac{2.5V}{64mA} = 39 \Omega $$
Given this, we can compute what the worst-case starting current is for a 5V supply:
$$ I_{start(pk)} = \frac{5V}{39 \Omega} = 128 mA$$
So, you need a 5 V supply capable of supplying 128 mA, at least for starting up. Note that since your supply was sagging pretty heavily under only 64 mA of load (5 V to 4.6 V is 8% sag), you probably want to consider another supply.