Typically contacts rated for AC and DC, whether operated by hand (switches) or a coil (a relay) will be rated for a much lower DC voltage. This is because an AC arc at the time of contact opening will tend to self quench when the AC crosses zero. However a DC arc will persist much longer (or indefinitely!) and is damaging to the contacts. There is a "DC Rule of Thumb" for switches that list an AC voltage rating only, which is that the highest AC current quoted for the switch should perform satisfactorily up to 30 volts DC. Your relay sounds like one of these.
Many people, used to AC power, don't realise how brutal DC can be, even at lower voltages. There have been many cases of destructive fires caused by using AC type components and techniques (switches, connections, cable terminations, etc) on DC solar installations. Careful study of this topic may save much heartache later. People think of batteries and say "it's only DC". In the early days of DC mains power, switch operators in power houses were sometimes provided with long handled wooden paddles to try to break the arcs formed when opening the bare knife switches, which dripped molten copper and emitted blinding light. If it didn't work, I think they probably ran for it.
AC switch 240v 10A rated, used to break 240v 7A DC