Proper grounding strategies in mixed signal circuits can be a complicated issue. According to the user manual for your microcontroller, VSSA is
Ground for analog power supply. On device package which do not have a dedicated VSSA pin, VSSA is internally connected to VSS.
Assuming your device package does have a separate VSSA pin, this app note from Analog Devices describes a good design practice for the VSS and VSSA pins.
Many ADCs and DACs have separate analog ground (AGND) and digital ground (DGND) pins. On the device data sheets, users are often advised to connect these pins together at the package. This seems to conflict with the advice to connect analog and digital ground at the power supplies, and, in systems with more than one converter, with the advice to join the analog and digital ground at a single point.
There is, in fact, no conflict. The labels, “analog ground” and “digital ground,” on these pins refer to the internal parts of the converter to which the pins are connected and not to the system grounds to which they must go. For an ADC, these two pins should generally be joined together and to the analog ground of the system. It is not possible to join the two pins within the IC package because the analog part of the converter cannot tolerate the voltage drop resulting from the digital current flowing in the bond wire to the chip. But they can be tied together externally.
Now onto your real question about whether to connect Vref- to VSS or VSSA. According to the chip user guide, Vref- is tied to VSSA internally, so you could actually leave this pin disconnected as long as you have a separate connection between VSS and VSSA on the PCB, and Vref- will just reference VSSA anyway. Alternatively you could still connect it to your analog ground on the board which should not make much of a difference if you have a good grounding strategy on the board.