The white spots are just leftover flux from when the board was assembled. Those 0.100" pin connectors were likely hand-soldered and some flux residue was left on the board. This is normal and doesn't impact the functioning in anyway.
Not all fluxes are created equal though. Many will begin to corrode metals if they aren't cleaned completely off the board.
On the other hand, there are fluxes called 'no-clean' fluxes that are inert and do not need to be washed off. This is the kind of flux you'll find leftover if a PCB has any residue.
All of the no-clean fluxes I've seen turn white if they're exposed to water.
Note that this does not mean the board got wet. If it was in storage, it would have been exposed to ambient humidity most likely. If it was stored somewhere and there was periods of high humidity during those 8 years, this would also turn those residues white.
In summary: it's harmless. Don't worry about it. If the device has any issues, it isn't from the white residue.