For mixed signal designs, layout and placementlayout and placement is generally far more critical than the specific decouplers used, although manufacturers will often state a decoupling scheme if they believe it to be critical.
The rule of thumb (as already noted) is 100nF per power pin and a bulk decoupler for larger components (such as processors, microcontrollers, large FPGAs).
Xilinx goes into quite some detail on this subject.