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Sep 24, 2013 at 16:46 comment added ChrisPhoenix Well, one difference is that the neutralized electrons are all through the conductor, while the excess electrons will be on the surface. I took the original question to be looking for effects like adding carriers to semiconductors; I don't expect any such effects here since conductors already have lots of carriers. In theory they might form Cooper pairs or something (which is what superconductors have) but I don't see why they would.
Sep 24, 2013 at 9:59 comment added Vasiliy Very nice intuition, but you forgot one crucial point: the charge of electrons present in neutral conductor is neutralized by the charge of nuclei. These additional electrons are not neutralized, therefore you can not assume that their contribution is the same as of the conduction electrons in a neutral conductor.
Sep 24, 2013 at 7:41 review Late answers
Sep 24, 2013 at 7:43
Sep 24, 2013 at 7:24 history answered ChrisPhoenix CC BY-SA 3.0