The fusing current for bare copper wire in free air is about 333 A. This can be higher or lower depending on how the air flows. This is a melting temperature of 1084oC
Most wires that we use are insulated so that they can be bundled and routed without shorting together or to other objects. Polyethylene (PE) melts at about 120oC. The thermal resistance from copper to air through the PE is much higher than from copper directly to air, so the temperature rises to a higher value for the same current flow.
Other insulating materials allow higher temperatures and so may allow higher currents.
For maximum safety from touching a too hot wire, the electrical codes often limit the max temperature to 60oC. This generally assumes an ambient temperature of about 25oC. Under these conditions the max current is about 30A dc or rms.
In addition to thermal resistance there is thermal capacitance. Together they form a time constant similar to the electrical time constant. Thus it takes time for heating and cooling to occur in response to a step change in current. So then it is the average current that determines the heating. So intermittently, large currents may be drawn as long as the average is ok and the pulse is short enough.
what is the advantage of a 2.2Ah 60C battery (132 amps), over a 2.2Ah 50C battery (110 amps) if they both already exceed the maximum current draw through the 10 gauge wire?
Well, let me say:
- Determine the load current draw. (average and peak)
- Select the battery,
- Select the wire gauge to suit the current draw, charging requirements and the temperature requirements.
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Wikipedia source for American Wire Gauges.