For completeness I would like to note that switching regulators that exhibit a SYNC terminal usually have that capability for another reason. While synchronizing to the MCU clock can be advantageous as described above, this is very rarely needed and is thus seldom done.
The real reason regulators can be synchronized is for the case when you have multiple regulators in your design. Then, by feeding all of them the same clock frequency but with different phase, you can make sure they are not switching at the same time, which reduces input voltage and current ripple, eases input filtering requirements, and reduces EMI phenomena.