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Soldering is the metallurgic process used to fix electronic components to a PCB, usually with a tin alloy. Soldering can be done by hand or automatic. PTH boards were usually wave soldered, SMT uses reflow technology.

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Desoldering Issues

I'm not able to see the picture (company firewall is evil). However it sounds like some type of conformal coating. A similar question was asked a while ago.
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