I've put together the circuit from the TI document Comparator with Hysteresis Reference Design using the same reference voltage to the noninverting input (Vth 2.3V - 2.7V). The Inverting input is connected to a voltage divider that depends on a thermistor, but for testing just a potentiometer.
I can confirm that the initial threshold voltage is 2.3V, and that the Power(5V) and GND are correct at pins 5 & 2. When I sweep the inverting input past the threshold voltages, the output never changes from GND.
Ultimately this output is driving the base of an NPN transistor to power a relay, but again, I never get 5V on the output. I actually pulled the first TLV3201 off the board and replaced it, but same issue.
What stupidity have I done?
EDIT - Reference circuit included for clarity.
EDIT2 - There is a low impedance path from the U2.1 (comparator output) to GND. Even on a number of blank boards. The board was not designed as such, but I measure 0.1 Ohms between those two pins. See the board image below. The output net is not directly grounded, the only way to GND is supposed to be via R2 + R3 (100K + 576K).