Depending on your converter topology (probably flyback), the combination of inductance, input voltage, and output power will determine your switching frequency.
Using a lower inductance will generally result in a higher switching frequency. Assuming discontinuous mode operation, generally...
$$f \ge \frac{W}{\frac{1}{2}I_{sat}^2*L} $$
For example 749196540 is 3.4uH and has saturation current of 4.18A.
$$\frac{45W}{\frac{1}{2}*4.18A^2*3.4uH} = 1.51MHz $$
We can calculate the switching frequency for all the parts in this series. The results are shown below.
Typically, one would expect that the frequency is at least 20% higher to account for efficiency losses.
What we see is that for this transformer series the available combinations of inductance and saturation current result in very high switching frequencies (and therefore high switching losses).
Wurth actually has a really good tool called Red Expert that can help you pick a transformer.
Another thing to consider is the on-time of your power switch. Generally the power switch can't be on for more than...
$$T \le \frac{I_{sat}*L}{V_{in}} $$
So for example...
$$\frac{4.18A*3.4uH}{120V} = 120ns $$
Which is actually pretty short. It may be too short if your switching transistor or controller chip can't switch that fast.