If it's an oldskool aircon unit it will have a big AC motor, usually asynchronous, so no rectifier is involved.
If it's a modern "inverter" unit, it'll have a rectifier and power factor correction circuit to turn your mains voltage into some higher DC voltage, about equal to the peak value of your AC. So if you're running it on 230V it'll make about 320V DC. Then an inverter generates three phase power to run the motor, with speed control.
This type of appliance can, in theory, run on DC, if the DC voltage is in the same range as the allowed input AC voltage. In practice, it may or may not, the absence of zero crossings may cause the PFC unit to behave in unexpected ways.
I don't see any reason why your aircon unit would use 50V DC anywhere.