In general power system operators do not have any way to control the angle of voltages of the buses in the grid. What are controllable are the power injections and voltage setpoints of generators. There are also switched shunt reactive power devices (capacitors & reactors) and some transformers' on-load tap changers, all of which mainly affect voltage magnitude and reactive power flows rather than voltage angles and active power flows.
For addressing phase angles, sometimes there are phase-angle transformers or more complicated power-electronic-based devices called FACTS, but for the most part the phase angles just are what they are based on the net power injections on the nodes of the system and the branches that are in service at the time. Active power will flow from buses with net generation toward buses with net load.
As a simple example for how you might reverse power flow on a line, suppose you have two areas connected by a single transmission line:
If there is more generation than load in Area A and more load than generation in Area B (where total generation minus load and losses across both areas is 0), then you will see power flowing on the transmission line from Area A to Area B as shown below.
Area A -->-->-->--> Area B
(P_gen > P_load) (P_gen < P_load)
In order to reverse the direction of power flow on the transmission line, Area A generation must be decreased and/or load increased and Area B generation must be increased and/or load decreased so that now Area B has more generation than load and Area A has more load than generation. Now active power will flow from Area B toward Area A.
Area A <--<--<--<-- Area B
(P_gen < P_load) (P_gen > P_load)