I'll assume this is the circuit you`re testing
Usually a voltmeter (PMMC) type:
Is a galvanometer with a HUGE series resistance (Mega ohm), such that a very small amount of current pass through it whenever this voltmeter is connected in parallel with a resistance
For the circuit shown
Voltage source is 3.3 V
Current = 0.0075 A
Load resistances = 220 Ω each
The voltage drop across each of the 220 Ω is 1.65 V = (0.0075 * 220)
BUT when you connect your voltmeter now
Assuming that: R:The voltmeter resistance = 10 MΩ
And you want to measure the drop across one of your resistances
so you'll now connect your voltmeter in PARALLEL with one of these 220 Ω resistances
Now you`re adding a parallel resistance with your load of value 10 MΩ
So the current is now not 0.0075 A since the circuit equivalent resistance is no longer the two series 220 Ω resistances only
its a combination of two parallel resistance 220 Ω,10 MΩ and a series resistance 220 Ω such that the equivalent resistance is now 439.9951 Ω (Almost less than 440)
so you'll not have the same amount of current (0.0075 A) but a slightly more amount of current in this case (0.00750008249 A) Almost 0.0075!
this in turn affects the voltage drop across each resistance by a very very small value that we usually neglect
So you'd expect a slightly smaller reading than the calculated value
Other factors also affects your reading such as