Well, we have the following transfer function:
$$\mathcal{H}\left(\text{s}\right):=\frac{\text{X}\left(\text{s}\right)}{\text{Y}\left(\text{s}\right)}=\frac{\left(1+10^{-\alpha}\cdot\text{s}\right)\left(1+10^{-\beta}\cdot\text{s}\right)}{\left(1+10^{-\gamma}\cdot\text{s}\right)\left(1+10^{-\epsilon}\cdot\text{s}\right)}\tag1$$
Where \$\alpha\in\mathbb{R}_{\ge0}\$, \$\beta\in\mathbb{R}_{\ge0}\$,\$\gamma\in\mathbb{R}_{\ge0}\$, and \$\epsilon\in\mathbb{R}_{\ge0}\$.
We can expand the RHS of the transfer function:
$$\mathcal{H}\left(\text{s}\right)=\frac{1+10^{-\beta}\cdot\text{s}+10^{-\alpha}\cdot\text{s}+10^{-\alpha}\cdot\text{s}\cdot10^{-\beta}\cdot\text{s}}{1+10^{-\epsilon}\cdot\text{s}+10^{-\gamma}\cdot\text{s}+10^{-\gamma}\cdot\text{s}\cdot10^{-\epsilon}\cdot\text{s}}=$$
$$\frac{1+\left(10^{-\alpha}+10^{-\beta}\right)\cdot\text{s}+10^{-\left(\alpha+\beta\right)}\cdot\text{s}^2}{1+\left(10^{-\gamma}+10^{-\epsilon}\right)\cdot\text{s}+10^{-\left(\gamma+\epsilon\right)}\cdot\text{s}^2}=$$
$$\frac{10^{-\left(\alpha+\beta\right)}\cdot\text{s}^2+\left(10^{-\alpha}+10^{-\beta}\right)\cdot\text{s}+1}{10^{-\left(\gamma+\epsilon\right)}\cdot\text{s}^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\cdot\text{s}+1}\tag2$$
Now, when we work with sinusoidial functions we can substitute \$\text{s}=\text{j}\omega\$:
$$\underline{\mathcal{H}}\left(\text{j}\omega\right)=\frac{10^{-\left(\alpha+\beta\right)}\cdot\left(\text{j}\omega\right)^2+\left(10^{-\alpha}+10^{-\beta}\right)\cdot\text{j}\omega+1}{10^{-\left(\gamma+\epsilon\right)}\cdot\left(\text{j}\omega\right)^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\cdot\text{j}\omega+1}=$$
$$\frac{1-10^{-\left(\alpha+\beta\right)}\omega^2+\left(10^{-\alpha}+10^{-\beta}\right)\omega\text{j}}{1-10^{-\left(\gamma+\epsilon\right)}\omega^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\omega\text{j}}\tag3$$
Now, we can take the argument on both sides:
$$\displaystyle\arg\left(\underline{\mathcal{H}}\left(\text{j}\omega\right)\right)=\arg\left(1-10^{-\left(\alpha+\beta\right)}\omega^2+\left(10^{-\alpha}+10^{-\beta}\right)\omega\text{j}\right)-\arg\left(1-10^{-\left(\gamma+\epsilon\right)}\omega^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\omega\text{j}\right)\tag4$$
So, we get a few different cases:
- When \$1-10^{-\left(\alpha+\beta\right)}\omega^2=0\$, we get:
$$\arg\left(1-10^{-\left(\alpha+\beta\right)}\omega^2+\left(10^{-\alpha}+10^{-\beta}\right)\omega\text{j}\right)=\frac{\pi}{2}\tag5$$
- When \$1-10^{-\left(\alpha+\beta\right)}\omega^2>0\$, we get:
$$\arg\left(1-10^{-\left(\alpha+\beta\right)}\omega^2+\left(10^{-\alpha}+10^{-\beta}\right)\omega\text{j}\right)=$$
$$\arctan\left(\frac{\left(10^{-\alpha}+10^{-\beta}\right)\omega}{1-10^{-\left(\alpha+\beta\right)}\omega^2}\right)\tag6$$
- When \$1-10^{-\left(\alpha+\beta\right)}\omega^2<0\$, we get:
$$\arg\left(1-10^{-\left(\alpha+\beta\right)}\omega^2+\left(10^{-\alpha}+10^{-\beta}\right)\omega\text{j}\right)=$$
$$\frac{\pi}{2}+\arctan\left(\frac{\left|1-10^{-\left(\alpha+\beta\right)}\omega^2\right|}{\left(10^{-\alpha}+10^{-\beta}\right)\omega}\right)\tag7$$
- When \$1-10^{-\left(\gamma+\epsilon\right)}\omega^2=0\$, we get:
$$\arg\left(1-10^{-\left(\gamma+\epsilon\right)}\omega^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\omega\text{j}\right)=\frac{\pi}{2}\tag8$$
- When \$1-10^{-\left(\gamma+\epsilon\right)}\omega^2>0\$, we get:
$$\arg\left(1-10^{-\left(\gamma+\epsilon\right)}\omega^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\omega\text{j}\right)=\arctan\left(\frac{\left(10^{-\gamma}+10^{-\epsilon}\right)\omega}{1-10^{-\left(\gamma+\epsilon\right)}\omega^2}\right)\tag9$$
- When \$1-10^{-\left(\gamma+\epsilon\right)}\omega^2<0\$, we get:
$$\arg\left(1-10^{-\left(\gamma+\epsilon\right)}\omega^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\omega\text{j}\right)=$$
$$\frac{\pi}{2}+\arctan\left(\frac{\left|1-10^{-\left(\gamma+\epsilon\right)}\omega^2\right|}{\left(10^{-\gamma}+10^{-\epsilon}\right)\omega}\right)\tag{10}$$
Now, we can this apply this to your problem. We know that \$\alpha=2\$, \$\beta=\frac{5}{2}\$, \$\gamma=0\$, and \$\epsilon=\frac{9}{2}\$. So we can work out the different cases:
- When \$\omega=100\sqrt[4]{10}\$, we get:
$$\arg\left(1-10^{-\left(\alpha+\beta\right)}\omega^2+\left(10^{-\alpha}+10^{-\beta}\right)\omega\text{j}\right)=\frac{\pi}{2}\tag{11}$$
- When \$0\le\omega<100\sqrt[4]{10}\$, we get:
$$\arg\left(1-10^{-\left(\alpha+\beta\right)}\omega^2+\left(10^{-\alpha}+10^{-\beta}\right)\omega\text{j}\right)=$$
$$\arctan\left(\frac{100\left(10+\sqrt{10}\right)\omega}{100000-\omega^2\sqrt{10}}\right)\tag{12}$$
- When \$\omega>100\sqrt[4]{10}\$, we get:
$$\arg\left(1-10^{-\left(\alpha+\beta\right)}\omega^2+\left(10^{-\alpha}+10^{-\beta}\right)\omega\text{j}\right)=$$
$$\frac{\pi}{2}+\arctan\left(\frac{\left|\omega^2\sqrt{10}-100000\right|}{100\left(10+\sqrt{10}\right)\omega}\right)\tag{13}$$
- When \$\omega=100\sqrt[4]{10}\$, we get:
$$\arg\left(1-10^{-\left(\gamma+\epsilon\right)}\omega^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\omega\text{j}\right)=\frac{\pi}{2}\tag{14}$$
- When \$0\le\omega<100\sqrt[4]{10}\$, we get:
$$\arg\left(1-10^{-\left(\gamma+\epsilon\right)}\omega^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\omega\text{j}\right)=$$
$$\arctan\left(\frac{\left(100000+\sqrt{10}\right)\omega}{100000-\omega^2\sqrt{10}}\right)\tag{15}$$
- When \$\omega>100\sqrt[4]{10}\$, we get:
$$\arg\left(1-10^{-\left(\gamma+\epsilon\right)}\omega^2+\left(10^{-\gamma}+10^{-\epsilon}\right)\omega\text{j}\right)=$$
$$\frac{\pi}{2}+\arctan\left(\frac{\left|\omega^2\sqrt{10}-100000\right|}{\left(100000+\sqrt{10}\right)\omega}\right)\tag{16}$$
If you uses Mathematica I wrote a code that you can use:
Plot[Piecewise[{{Pi/2, \[Omega] ==
100*10^(1/
4)}, {ArcTan[(100*(10 +
Sqrt[10])*\[Omega])/(100000 - \[Omega]^2*Sqrt[10])],
0 <= \[Omega] < 100*10^(1/4)}, {(Pi/2) +
ArcTan[Abs[\[Omega]^2*Sqrt[10] -
100000]/(100*(10 + Sqrt[10])*\[Omega])], \[Omega] >
100*10^(1/4)}}] -
Piecewise[{{Pi/2, \[Omega] ==
100*10^(1/
4)}, {ArcTan[((100000 +
Sqrt[10])*\[Omega])/(100000 - \[Omega]^2*Sqrt[10])],
0 <= \[Omega] < 100*10^(1/4)}, {(Pi/2) +
ArcTan[Abs[\[Omega]^2*Sqrt[10] -
100000]/((100000 + Sqrt[10])*\[Omega])], \[Omega] >
100*10^(1/4)}}], {\[Omega], 10, 10^(3/2)},
AxesLabel -> {HoldForm[\[Omega][rad/s]], HoldForm[Arg[H[s]]]},
PlotLabel -> HoldForm[Argument], LabelStyle -> {GrayLevel[0]}]
The output, gives:
Plotting a bigger range, gives: