The Main and Rx-Diversity antenna interfaces are both used for cellular radio communication in a MIMO (multiple-input multiple-output) configuration. They should each be connected to an antenna that supports the LTE frequency bands (see data sheet). To the extent possible, the antennas should be separated in space, and again if possible, polarized differently.
A single radio propagation channel is subject to fading effects caused by multipath reflections, antenna pattern irregularities, and other factors. While a second (diversity) channel may also be subject to its own fading effects, they may not the same as (i.e. correlated with) the first channel's fading. In basic diversity reception systems, the receiver can switch between the antennas to pick the best signal. Your modem is more sophisticated and can combine the two signals to enhance their strength, or even receive on two channels simultaneously to achieve faster speeds.