Your use of the smith chart is correct, but your numbers are a little off due to the wavelength you used (6.5mm).
In stripline, the fields are completely contained inside the substrate. The fields are partially in air around a microstrip line, resulting in an effective permittivity which is lower than the relative permittivity of the substrate. Wavelength can be calculated using the effective permittivity or the delay (Tpd). Both are available from your impedance calculator. Er effective is 3.0635. Tpd is 5.8e-9 s/m.
\$ Wavelength = \frac{c}{\sqrt{E_{r}} \cdot f} = \frac{1}{T_{pd} \cdot f} \$
\$ Wavelength(w/ E_{r}) = \frac{c}{\sqrt{E_{r}} \cdot f} = 6.5 mm \$
\$ Wavelength(w/ E_{eff}) = \frac{c}{\sqrt{E_{eff}} \cdot f} = 7.1 mm \$
\$ Wavelength(w/ T_{pd}) = \frac{1}{T_{pd} \cdot f} = 7.1 mm \$
The difference between 6.5mm and 7.1mm may seem small, but check out the difference in return loss.
\$ Z_{out}(\Lambda:6.5mm) = 33-j24 \Omega \$ >>>> \$ ORL=9dB \$
\$ Z_{out}(\Lambda:7.1mm) = 46-j14 \Omega \$ >>>> \$ ORL=16dB \$
For a sanity check, match from the load to the conjugate of the generator. In other words, start at a load of \$50\Omega\$ and go towards the chip. You'll end up around \$20.8+j20.2\Omega\$. This is typical for most output stages, since they're usually low resistance and capacitive.
Your method of matching will provide a decent ballpark, but I'd like to point out a few important sources of error.
- Tx & Txx are intended to be 100ohm differential signals. The small spacing between them produces an additional shunt capacitance. You need to include the extra capacitance, or use a coupled line model.
- The datasheet doesn't say how they measured the Tx/Txx load impedances. Did they measure at the PCB output port and try to de-embed everything up to the chip? I'm skeptical of the accuracy without knowing where they came from. Additionally, I think these are the impedances looking into the Tx/Txx ports. I would call the load impedance the conjugate of the printed values, or the impedance presented to the Tx/Txx ports. It's all unclear.
- The package pad (footprint) will have a different impact on a different board stackup.
- I don't see anything to cancel mismatch from the launchers. The launchers will perform differently on a different board stackup.
The matching network they used is simple and probably low loss. I guess you could call it a stepped-impedance match. I don't know. It's a plus to avoid shunt components or stubs, and the high Q resonances they might produce.