Since you're doing a DC operating point analysis from the perspective of the DC signal, the pulse source is a ground since alternating sources act as short circuits. If you add C1 and C2 together, you can simplify the circuit to just a 5V DC source connected across two capacitors: C12 = 2pF and C3 = 1pF.
For capacitors in series, each capacitor has the same charge on it. Therefore Q12 = Q3 = Q. If we further reduce the series capacitors C12 and C3 to
Ct = = (1/C12 + 1/C3)^-1 = (1/2pF + 1/1pF)^-1 = 2/3pF,
we know this simplified capacitor has a voltage of 5V and a charge of 2Q, since charges in series add. So, since CV=Q:
2/3pF * 5V = 2Q -> Q = 1.6667 pC
Now, if we go back to the C12 and C3 combination, Q is the charge across C3. And again from CV=Q, we have:
C3 * V = Q -> V = 1.6667pC/1pF = 1.6667 V
or V = 5/3V